Requirements of marine engineering steel for chemical composition

The main factors affecting the properties of marine engineering steel are chemical composition, melting and casting, rolling and heat treatment process, among which sulfur and phosphorus content directly affect the properties of marine engineering steel plate thickness direction. Sulphur is the most serious segregation element in continuous casting slab. Sulphur can cause hot brittleness of marine engineering steel and cracks in marine engineering steel during forging at high temperature. There are many looseness and blowhole during welding.

Phosphorus is a high segregation element next to sulphur in continuous casting billet of marine engineering steel, and the diffusion rate of phosphorus in iron solid solution is very small, so the segregation of phosphorus is difficult to eliminate, which seriously affects the properties of marine engineering steel. Phosphorus is dissolved in ferrite in the form of solid solution, which is very brittle. The formed phosphorus-rich zone promotes the brittleness of marine engineering steel and reduces its plasticity, toughness and weldability. It is easy to cause cracks in marine engineering steel during hot working and cracks in welding. Phosphorus is an element that reduces the surface tension of marine engineering steel. With the increase of phosphorus content, the surface tension of molten marine engineering steel decreases significantly, which reduces the crack resistance of marine engineering steel.

Therefore, there are strict requirements for sulfur and phosphorus content in marine engineering steel plates for offshore platforms, among which the sulfur content is strictly controlled.

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